Trigun - 4: Love & Peace

Episode:4: Love & Peace
Meryl and Milly, along with the beautiful daughter of the town's Mayor, are taken hostage in a saloon by four angry gunmen. Apparently through sheer negligence, Vash walks in and is captured as well.
Stretch: At one point Vash refuses to shoot a villain he has at his mercy. If I'm not mistaken, he utters the word "Rem" just before lowering his gun (probably the first time that name is used in the series). In fact, I don't think Vash fires a single shot in the entire episode. He does perform some elaborate acrobatics in order to free a tied-up hostage and recover his own gun.

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